Bürgi, J J; Mariz, R; Gatti, M; Drinkel, E; Luan, X; Blumentritt, S; Linden, Anthony; Dorta, R (2009). Unprecedented selectivity via electronic substrate recognition in the 1,4-addition to cyclic olefins using a chiral disulfoxide Rhodium catalyst. Angewandte Chemie Internationale Edition, 48(15):2768-2771.
From zero to hero? Sulfoxides are generally not considered useful ligand entities in asymmetric metal catalysis. However, a chiral disulfoxide as a chelating ligand in the rhodium-catalyzed 1,4-addition of aryl boronic acids to cyclic,-unsaturated ketones and esters gives impressive catalytic results, thus opening the door to future applications of this new chiral ligand class.
From zero to hero? Sulfoxides are generally not considered useful ligand entities in asymmetric metal catalysis. However, a chiral disulfoxide as a chelating ligand in the rhodium-catalyzed 1,4-addition of aryl boronic acids to cyclic,-unsaturated ketones and esters gives impressive catalytic results, thus opening the door to future applications of this new chiral ligand class.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Uncontrolled Keywords: | General Chemistry, Catalysis |
| Language: | English |
| Date: | 2009 |
| Deposited On: | 18 Feb 2010 18:16 |
| Last Modified: | 28 Jun 2022 08:12 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1433-7851 |
| Funders: | Alfred Werner Foundation, SNF, Roche Research Foundation |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/anie.200900429 |
| Project Information: |
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Bürgi, J J