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Braband, H; Imstepf, S; Felber, M; Spingler, B; Alberto, R (2010). Triazacyclohexane (tach) complexes of high-valent rhenium: syntheses of [(R(3)tach)ReO(3)](+) (R = -CH(3), -CH(2)C(6)H(5)) and its substitution reactions. Inorganic Chemistry, 49(4):1283-1285.
N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the (R(3)tach)ReO3](+) type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the ReO3](+) motif for Re-VII complexes.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Inorganic Chemistry |
| Language: | English |
| Date: | 2010 |
| Deposited On: | 23 Feb 2011 18:35 |
| Last Modified: | 05 Mar 2025 02:40 |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| Funders: | Swiss National Science Foundation |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1021/ic902114p |
| PubMed ID: | 20055461 |
| Other Identification Number: | ISI:000274240700005 |
| Project Information: |
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Braband, H