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Barman, S; Furukawa, H; Blacque, O; Venkatesan, K; Yaghi, O M; Berke, H (2010). Azulene based metal-organic frameworks for strong adsorption of H-2. Chemical Communications, 46(42):7981-7983.
Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | 2010 |
| Deposited On: | 23 Feb 2011 16:39 |
| Last Modified: | 05 Sep 2024 01:40 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1039/c0cc02589e |
| PubMed ID: | 20871899 |
| Other Identification Number: | ISI:000283260400033 |
Barman, S