Semenov, S N; Taghipourian, S F; Blacque, O; Fox, T; Venkatesan, K; Berke, H (2010). An iron-capped metal−organic polyyne: {[Fe](C≡C)2[W]≡CC≡CC≡[W](C≡C)2[Fe]}. Journal of the American Chemical Society, 132(22):7584-7585.
The organometallic conjugated complex H(C C)(2)W] CC CC W](C C)(2)H {W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.
The organometallic conjugated complex H(C C)(2)W] CC CC W](C C)(2)H {W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.
| Other titles: | An iron-capped metal-organic polyyne: {[Fe](C[triple bond]C)2[W][triple bond]CC[triple bond]CC[triple bond][W](C[triple bond]C)2[Fe]} |
|---|---|
| Item Type: | Journal Article, refereed, original work |
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry Life Sciences > Biochemistry Physical Sciences > Colloid and Surface Chemistry |
| Language: | English |
| Date: | 2010 |
| Deposited On: | 23 Feb 2011 17:35 |
| Last Modified: | 30 Jul 2020 01:00 |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1021/ja102570f |
| PubMed ID: | 20465259 |
| Other Identification Number: | ISI:000278837100010 |
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Semenov, S N