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An iron-capped metal−organic polyyne: {[Fe](C≡C)2[W]≡CC≡CC≡[W](C≡C)2[Fe]}


Semenov, S N; Taghipourian, S F; Blacque, O; Fox, T; Venkatesan, K; Berke, H (2010). An iron-capped metal−organic polyyne: {[Fe](C≡C)2[W]≡CC≡CC≡[W](C≡C)2[Fe]}. Journal of the American Chemical Society, 132(22):7584-7585.

Abstract

The organometallic conjugated complex H(C C)(2)W] CC CC W](C C)(2)H {W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.

Abstract

The organometallic conjugated complex H(C C)(2)W] CC CC W](C C)(2)H {W] = W(dppe)(2); dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.

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Additional indexing

Other titles:An iron-capped metal-organic polyyne: {[Fe](C[triple bond]C)2[W][triple bond]CC[triple bond]CC[triple bond][W](C[triple bond]C)2[Fe]}
Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2010
Deposited On:23 Feb 2011 17:35
Last Modified:17 Feb 2018 18:49
Publisher:American Chemical Society
ISSN:0002-7863
OA Status:Closed
Publisher DOI:https://doi.org/10.1021/ja102570f
PubMed ID:20465259
Other Identification Number:ISI:000278837100010

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