Mlostoń, Grzegorz; Jasiński, M; Heimgartner, H (2011). A straigthforward access to (imidazol-2-yl)acetates by reaction of 2-unsubstituted imidazole 3-oxides with dimethyl acetylenedicarboxylate. European Journal of Organic Chemistry, 2011(13):2542-2547.
A new method for the preparation of 1,4,5-trisubstituted (imidazol-2-yl)acetates, based on the reaction of the corresponding imidazole 3-oxides with dimethyl acetylenedicarboxylate (DMAD) is described. Formation of the products is rationalized by a formal 1,3-dipolar cycloaddition and subsequent oxaloyl cleavage.
A new method for the preparation of 1,4,5-trisubstituted (imidazol-2-yl)acetates, based on the reaction of the corresponding imidazole 3-oxides with dimethyl acetylenedicarboxylate (DMAD) is described. Formation of the products is rationalized by a formal 1,3-dipolar cycloaddition and subsequent oxaloyl cleavage.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry |
| Language: | English |
| Date: | 2011 |
| Deposited On: | 02 May 2011 11:07 |
| Last Modified: | 28 Jun 2022 15:39 |
| Publisher: | Wiley-Blackwell |
| ISSN: | 1099-0690 |
| Funders: | Rector of the University of Lodz, Grant 505/712/R |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/ejoc.201001594 |
Mlostoń, Grzegorz