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A straigthforward access to (imidazol-2-yl)acetates by reaction of 2-unsubstituted imidazole 3-oxides with dimethyl acetylenedicarboxylate

Mlostoń, Grzegorz; Jasiński, M; Heimgartner, H (2011). A straigthforward access to (imidazol-2-yl)acetates by reaction of 2-unsubstituted imidazole 3-oxides with dimethyl acetylenedicarboxylate. European Journal of Organic Chemistry, 2011(13):2542-2547.

Abstract

A new method for the preparation of 1,4,5-trisubstituted (imidazol-2-yl)acetates, based on the reaction of the corresponding imidazole 3-oxides with dimethyl acetylenedicarboxylate (DMAD) is described. Formation of the products is rationalized by a formal 1,3-dipolar cycloaddition and subsequent oxaloyl cleavage.

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry
Language:English
Date:2011
Deposited On:02 May 2011 11:07
Last Modified:05 Jul 2025 01:41
Publisher:Wiley-Blackwell
ISSN:1099-0690
Funders:Rector of the University of Lodz, Grant 505/712/R
OA Status:Closed
Publisher DOI:https://doi.org/10.1002/ejoc.201001594

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