Dong, H; Berke, H (2011). A mild and efficient rhenium-catalyzed transfer hydrogenation of terminal olefins using alcoholysis of amine-borane adducts as a reducing system. Journal of Organometallic Chemistry, 696(9):1803-1808.
ReBr(2)(NO)(CH(3)CN)(PTA)(2)] (PTA - 1, 3, 5-triaza-7-phosphaadamantane) catalyzes the alcoholysis of ammonia-borane and amine-boranes and the catalytic transfer hydrogenations of various terminal olefins. Excellent yields were achieved at 70 degrees C in isopropanol using tBuOK as a co-catalyst affording TOF values up to 396 h(-1). (C) 2011 Elsevier B.V. All rights reserved.
ReBr(2)(NO)(CH(3)CN)(PTA)(2)] (PTA - 1, 3, 5-triaza-7-phosphaadamantane) catalyzes the alcoholysis of ammonia-borane and amine-boranes and the catalytic transfer hydrogenations of various terminal olefins. Excellent yields were achieved at 70 degrees C in isopropanol using tBuOK as a co-catalyst affording TOF values up to 396 h(-1). (C) 2011 Elsevier B.V. All rights reserved.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Life Sciences > Biochemistry
Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry Physical Sciences > Inorganic Chemistry Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | May 2011 |
| Deposited On: | 12 Mar 2012 16:09 |
| Last Modified: | 23 Jan 2022 21:30 |
| Publisher: | Elsevier |
| ISSN: | 0022-328X |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1016/j.jorganchem.2011.01.027 |
| Other Identification Number: | ISI:000290019300013 |
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Dong, H