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When two metal centres are needed instead of one: exclusive induction of Z-DNA by dinuclear metal complexes


Medina-Molner, Alfredo; Spingler, Bernhard (2012). When two metal centres are needed instead of one: exclusive induction of Z-DNA by dinuclear metal complexes. Chemical Communications, 48(14):1961-1963.

Abstract

The B- to Z-DNA transition was very efficiently induced by dinuclear nickel and copper complexes based on the 1,3-bis(1,5,9-triazacyclododecyl) propane ligand but not by the corresponding mononuclear complexes. This dramatically different behaviour is explained by the formation of a macrochelate of the dinuclear complexes to the DNA.

Abstract

The B- to Z-DNA transition was very efficiently induced by dinuclear nickel and copper complexes based on the 1,3-bis(1,5,9-triazacyclododecyl) propane ligand but not by the corresponding mononuclear complexes. This dramatically different behaviour is explained by the formation of a macrochelate of the dinuclear complexes to the DNA.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials
Physical Sciences > Ceramics and Composites
Physical Sciences > General Chemistry
Physical Sciences > Surfaces, Coatings and Films
Physical Sciences > Metals and Alloys
Physical Sciences > Materials Chemistry
Language:English
Date:2012
Deposited On:17 Oct 2012 11:41
Last Modified:19 Aug 2022 10:00
Publisher:Royal Society of Chemistry
ISSN:1359-7345
OA Status:Closed
Publisher DOI:https://doi.org/10.1039/c2cc16483c
Other Identification Number:ISI:000299290200003