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Synthesis and structure of a hydrogenated zinc hemiporphyrazine


Huber, Sabrina M; Mata, Guillaume; Linden, Anthony; Luedtke, Nathan W (2013). Synthesis and structure of a hydrogenated zinc hemiporphyrazine. Chemical Communications, 49:4280-4282.

Abstract

Palladium-catalyzed hydrogenation of an octahedral zinc trans-ditriflate hemiporphyrazine “HpH2Zn(OTf)2” furnishes a new macrocycle “HpH6Zn(OTf)2”. This reaction is fully reversible upon heating in nitrobenzene, and the conversion is easily monitored by changes in color and fluorescence properties. The reversible cycling between these molecules may find future applications in hemiporphyrazine-based catalysts and/or hydrogen storage devices.

Abstract

Palladium-catalyzed hydrogenation of an octahedral zinc trans-ditriflate hemiporphyrazine “HpH2Zn(OTf)2” furnishes a new macrocycle “HpH6Zn(OTf)2”. This reaction is fully reversible upon heating in nitrobenzene, and the conversion is easily monitored by changes in color and fluorescence properties. The reversible cycling between these molecules may find future applications in hemiporphyrazine-based catalysts and/or hydrogen storage devices.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials
Physical Sciences > Ceramics and Composites
Physical Sciences > General Chemistry
Physical Sciences > Surfaces, Coatings and Films
Physical Sciences > Metals and Alloys
Physical Sciences > Materials Chemistry
Language:English
Date:2013
Deposited On:05 Feb 2013 12:24
Last Modified:23 Jan 2022 23:37
Publisher:Royal Society of Chemistry (RSC)
ISSN:1359-7345
OA Status:Green
Publisher DOI:https://doi.org/10.1039/c2cc37151k

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