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Immobilization of Chiral Bifunctional Organocatalysts on Poly(methylhydrosiloxane)


Puglisi, Alessandra; Benaglia, Maurizio; Annunziata, Rita; Siegel, Jay S (2012). Immobilization of Chiral Bifunctional Organocatalysts on Poly(methylhydrosiloxane). ChemCatChem, 4(7):972-975.

Abstract

Takemoto promotes: Enantiomerically pure bifunctional chiral catalysts are immobilized on poly(methylhydrosiloxane). A supported Takemoto-type catalyst promoted the diethyl malonate addition to nitrostyrene in fair to good yields and up to 83 % ee, and its recyclability is demonstrated.

Abstract

Takemoto promotes: Enantiomerically pure bifunctional chiral catalysts are immobilized on poly(methylhydrosiloxane). A supported Takemoto-type catalyst promoted the diethyl malonate addition to nitrostyrene in fair to good yields and up to 83 % ee, and its recyclability is demonstrated.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:July 2012
Deposited On:18 Feb 2013 15:59
Last Modified:24 Sep 2019 19:12
Publisher:Wiley-Blackwell
ISSN:1867-3880
OA Status:Closed
Publisher DOI:https://doi.org/10.1002/cctc.201200114

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