Alberto, Roger; Bergamaschi, Greta; Braband, Henrik; Fox, Thomas; Amendola, Valeria (2012). 99Tco4−: Selective recognition and trapping in aqueous solution. Angewandte Chemie Internationale Edition, 51(39):9772-9776.
Too hot to handle: Unprecedented affinity and specificity for 99TcO4− in aqueous solution was shown with the p-xylyl azacryptand in the hexaprotonated form (see scheme). A crystal structure of the complex reveals how the anion fits within the cavity of the cage, and the formation of multiple H-bond interactions with protonated amino groups stabilize the adduct.
Too hot to handle: Unprecedented affinity and specificity for 99TcO4− in aqueous solution was shown with the p-xylyl azacryptand in the hexaprotonated form (see scheme). A crystal structure of the complex reveals how the anion fits within the cavity of the cage, and the formation of multiple H-bond interactions with protonated amino groups stabilize the adduct.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Uncontrolled Keywords: | General Chemistry, Catalysis |
| Language: | English |
| Date: | 2012 |
| Deposited On: | 04 Mar 2013 13:32 |
| Last Modified: | 24 Jan 2022 00:15 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1433-7851 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/anie.201205313 |
Alberto, Roger