Mlostoń, Grzegorz; Depczynski, Robert; Woznicka, Marta; Laur, Peter; Englert, Ulli; Hu, Chunhua; Heimgartner, Heinz (2005). Sulfur addition to aldimines: thioamides, not thiaziridines, as products; revision of an old report. Journal of Sulfur Chemistry, 26(2):111-117.
The reaction of 4-(phenylimino)butan-2-ol with ammonium polysulfide in refluxing EtOH yields 3-hydroxy-N-phenylbutanethioamide as the only isolated product. The structure has been established by single-crystal X-ray diffraction. Treatment of N-benzylidenamines with ammonium polysulfide has proven a general method for the preparation of thiobenzamides.
The reaction of 4-(phenylimino)butan-2-ol with ammonium polysulfide in refluxing EtOH yields 3-hydroxy-N-phenylbutanethioamide as the only isolated product. The structure has been established by single-crystal X-ray diffraction. Treatment of N-benzylidenamines with ammonium polysulfide has proven a general method for the preparation of thiobenzamides.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > General Chemistry |
| Language: | English |
| Date: | April 2005 |
| Deposited On: | 25 Apr 2013 09:44 |
| Last Modified: | 24 Jan 2022 00:51 |
| Publisher: | Taylor & Francis |
| ISSN: | 1741-5993 |
| Funders: | Polish State Committee for Scientific Research (Grant No. 4 T09A 046 25), F. Hoffmann-La Roche AG, Basel |
| Additional Information: | This is an Author's Accepted Manuscript of an article published in Mloston, Grzegorz; Depczynski, Robert; Woznicka , Marta; Laur, Peter; Englert, Ulli; Hu, Chunhua; Heimgartner, Heinz (2005). Sulfur addition to aldimines: thioamides, not thiaziridines, as products; revision of an old report. Journal of Sulfur Chemistry, 26(2):111-117. Copyright Taylor & Francis, available online at: http://www.tandfonline.com/10.1080/17415990500056788 |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1080/17415990500056788 |
Mlostoń, Grzegorz