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Trimiño, Maria I García; Linden, Anthony; Heimgartner, Heinz; Macias Cabrera, Arturo (1993). 3-(Acylamino)-3-amino-2-nitroacrylonitriles from N-Acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates. Helvetica Chimica Acta, 76:2817-2829.
Reaction of N-acyI-3,3-diamino-2-nitroacrylthioamides 1 with MeI at room temperature leads to N-acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates 2 in moderate yields. The latter react with Hg(OAc)2 in DMF yielding 3-(acylamino)-3-amino-2-nitroacrylonitriles 8. The structures of 2a and 8a were established by X-ray crystallography.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry Life Sciences > Drug Discovery Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry Physical Sciences > Inorganic Chemistry |
| Uncontrolled Keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis |
| Language: | English |
| Date: | 1993 |
| Deposited On: | 26 Dec 2013 09:44 |
| Last Modified: | 10 May 2025 01:37 |
| Publisher: | Wiley-Blackwell Publishing, Inc. |
| ISSN: | 0018-019X |
| Funders: | Swiss Federal Government (National Scholarship for Foreign Students) |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/hlca.19930760808 |
Trimiño, Maria I García