Tromm, Peter-Claus; Heimgartner, Heinz (1990). Eine neue 1,3-Oxathiolan-Synthese: Spirocyclische 1,3-0xathiolane aus der Lewis-Säure katalysierten Umsetzung von 1,3-Thiazol-5(4H)-thionen mit Oxiranen. Helvetica Chimica Acta, 73(8):2287-2294.
Abstract
The BF3.Et2O-catalyzed reaction of 2,4,4-trisubstituted 1,3-thiazole-5(4H)-thiones 13 with alkyl- and phenyl-substituted oxiranes 7 in CH2Cl2 at room temperature leads, in very good yields, to 1-oxa-4,6-dithia-8- azaspiro[4.4]non-7-enes 14 and 15.
Other titles: | A New 1,3-Oxathiolane Synthesis: Spirocyclic 1,3-Oxathiolanes from the Lewis-Acid-Catalyzed Reaction of 1,3-Thiazole-5(4H)-thiones and Oxiranes |
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Item Type: | Journal Article, refereed, original work |
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Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
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Dewey Decimal Classification: | 540 Chemistry |
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Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry
Life Sciences > Drug Discovery
Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry
Physical Sciences > Inorganic Chemistry |
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Uncontrolled Keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis |
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Language: | German |
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Date: | 1990 |
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Deposited On: | 27 Mar 2014 10:48 |
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Last Modified: | 11 Jul 2025 01:35 |
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Publisher: | Wiley-Blackwell Publishing, Inc. |
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ISSN: | 0018-019X |
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Funders: | Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung, F. Hoffmann-La Roche AG, Basel |
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OA Status: | Closed |
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Publisher DOI: | https://doi.org/10.1002/hlca.19900730825 |
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Project Information: | - Funder: SNSF
- Grant ID:
- Project Title: Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung
- Funder:
- Grant ID:
- Project Title: F. Hoffmann-La Roche AG, Basel
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