Abstract
On irradiation in the presence of Fe(CO)5, the allenic amides and imides showed a similar course of complexation to that of esters and lactones, respectively, e.g. the amides of type 10 led to diiron complexes of type 11 (Scheme 3 ), whereas the imide 12 yielded a mixture of a dinuclear and two mononuclear complexes (13-15, Scheme 4). The racemic ester 6 also gave mononuclear (7a, 7b, and 9) and dinuclear complexes (8a and 8b; Scheme 2). In case of the allenic acid 4, only complexation of type 5 was observed (Scheme 1).
| Item Type: | Journal Article, refereed, original work |
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| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
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| Dewey Decimal Classification: | 540 Chemistry |
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| Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry
Life Sciences > Drug Discovery
Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry
Physical Sciences > Inorganic Chemistry |
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| Uncontrolled Keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis |
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| Language: | English |
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| Date: | 1990 |
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| Deposited On: | 27 Mar 2014 15:29 |
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| Last Modified: | 11 May 2025 01:36 |
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| Publisher: | Wiley-Blackwell Publishing, Inc. |
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| ISSN: | 0018-019X |
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| Funders: | Swiss National Science Foundation, F. Hoffmann-La Roche AG, Basel |
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| OA Status: | Closed |
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| Publisher DOI: | https://doi.org/10.1002/hlca.19900730619 |
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| Project Information: | - Funder: SNSF
- Grant ID:
- Project Title: Swiss National Science Foundation
- Funder:
- Grant ID:
- Project Title: F. Hoffmann-La Roche AG, Basel
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Trifonov, Latchezar S