Jenny, Christjohannes; Obrecht, Daniel; Heimgartner, Heinz (1982). Additionsreaktionen von 2-Thiazolin-5-thionen mit Acetylenen. Helvetica Chimica Acta, 65(8):2583-2586.
Addition Reactions of 2-Thiazolin-5-thiones with Acetylenes.
The reaction of the 2-thiazolin-5-thiones 1 and 5, respectively, with acetylene carboxylates yields mainly 1,4-dithiafulvenes of type 3. In the presence of the acetylenic compounds, the 1,4-dithiafulvenes undergo an isomerization to give the corresponding 2,3-dihydrothiophene-2-thiones 4.
Addition Reactions of 2-Thiazolin-5-thiones with Acetylenes.
The reaction of the 2-thiazolin-5-thiones 1 and 5, respectively, with acetylene carboxylates yields mainly 1,4-dithiafulvenes of type 3. In the presence of the acetylenic compounds, the 1,4-dithiafulvenes undergo an isomerization to give the corresponding 2,3-dihydrothiophene-2-thiones 4.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry Life Sciences > Drug Discovery Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry Physical Sciences > Inorganic Chemistry |
| Language: | German |
| Date: | 1982 |
| Deposited On: | 24 Jul 2014 07:25 |
| Last Modified: | 12 Nov 2023 02:38 |
| Publisher: | Wiley-Blackwell |
| ISSN: | 0018-019X |
| Funders: | Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung, F. Hoffmann-La Roche & Co. AG, Basel |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1002/hlca.19820650829 |
| Project Information: |
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Jenny, Christjohannes