Publication: Proximity-Driven Magnetic Coupling between an Open-Shell Nanographene and a Rare-Earth Surface Alloy
Proximity-Driven Magnetic Coupling between an Open-Shell Nanographene and a Rare-Earth Surface Alloy
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Bassi, N., Wilhelm, J., Krane, N., Xiang, F., Čmelová, P., Turco, E., Gargiani, P., Pignedoli, C. A., Juríček, M., Fasel, R., Korytár, R., & Ruffieux, P. (2025). Proximity-Driven Magnetic Coupling between an Open-Shell Nanographene and a Rare-Earth Surface Alloy. ACS Nano, 19(38), 33868–33878. https://doi.org/10.1021/acsnano.5c09052
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Abstract
Open-shell nanographenes have attracted significant attention due to their structurally tunable spin ground state. While most characterization has been conducted on weakly interacting substrates such as noble metals, the influence of magnetic surfaces remains largely unexplored. In this study, we investigate how TbAu, a rare-earth-element-based surface alloy, affects the magnetic properties of phenalenyl (or [2]triangulene (2T)), the smallest spin-1/2 nanographene. Scanning tunneling spectroscopy (STS) measurements reveal a striking c
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- Bassi, Nicolò
- Wilhelm, Jan
- Krane, Nils
- Xiang, Feifei
- Čmelová, Patrícia
- Turco, Elia
- Gargiani, Pierluigi
- Pignedoli, Carlo A
- Juríček, Michal
- Fasel, Roman
- Korytár, Richard
- Ruffieux, Pascal
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Bassi, N., Wilhelm, J., Krane, N., Xiang, F., Čmelová, P., Turco, E., Gargiani, P., Pignedoli, C. A., Juríček, M., Fasel, R., Korytár, R., & Ruffieux, P. (2025). Proximity-Driven Magnetic Coupling between an Open-Shell Nanographene and a Rare-Earth Surface Alloy. ACS Nano, 19(38), 33868–33878. https://doi.org/10.1021/acsnano.5c09052