Publication: Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks
Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks
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Zhang, K., Shen, Y., Liu, J., Spingler, B., & Duttwyler, S. (2018). Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks. Chemical Communications, 54(14), 1698–1701. https://doi.org/10.1039/c7cc07724f
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Abstract
The crystal structure of the deprotonated monocarba-closododecaborate [12-CN-CB11H11]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.
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- Zhang, Kang
- Shen, Yunjun
- Liu, Jiyong
- Duttwyler, Simon
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Zhang, K., Shen, Y., Liu, J., Spingler, B., & Duttwyler, S. (2018). Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks. Chemical Communications, 54(14), 1698–1701. https://doi.org/10.1039/c7cc07724f