Publication: An Iridium-Stabilized Borenium Intermediate
An Iridium-Stabilized Borenium Intermediate
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Hamdaoui, M., Liu, F., Cornaton, Y., Lu, X., Shi, X., Zhang, H., Liu, J., Spingler, B., Djukic, J.-P., & Duttwyler, S. (2022). An Iridium-Stabilized Borenium Intermediate. Journal of the American Chemical Society, 144, 18359–18374. https://doi.org/10.1021/jacs.2c06298
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Abstract
Exploration of new organometallic systems based on polyhedral boron clusters has the potential to solve challenging chemical problems such as the stabilization of reactive intermediates and transition-state-like species postulated for E–H (E = H, B, C, Si) bond activation reactions. We report on facile and clean B–H activation of a hydroborane by a new iridium boron cluster complex. The product of this reaction is an unprecedented and fully characterized transition metal-stabilized boron cation or borenium. Moreover, this intermediate
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- Hamdaoui, Mustapha
- Liu, Fan
- Cornaton, Yann
- Lu, Xingyu
- Shi, Xiaohuo
- Zhang, Huan
- Liu, Jiyong
- Djukic, Jean-Pierre
- Duttwyler, Simon
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Hamdaoui, M., Liu, F., Cornaton, Y., Lu, X., Shi, X., Zhang, H., Liu, J., Spingler, B., Djukic, J.-P., & Duttwyler, S. (2022). An Iridium-Stabilized Borenium Intermediate. Journal of the American Chemical Society, 144, 18359–18374. https://doi.org/10.1021/jacs.2c06298
