Publication: A Samarium Rod‐MOF With Benzophenone‐4,4´‐Dicarboxylate Linker: A Catalyst for Glycerol Acetalization to Solketal
A Samarium Rod‐MOF With Benzophenone‐4,4´‐Dicarboxylate Linker: A Catalyst for Glycerol Acetalization to Solketal
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Hajiashrafi, T., Afzali, N., Tarighi, S., Rudbari, H. A., & Blacque, O. (2025). A Samarium Rod‐MOF With Benzophenone‐4,4´‐Dicarboxylate Linker: A Catalyst for Glycerol Acetalization to Solketal. Applied Organometallic Chemistry, 39(6), e70151. https://doi.org/10.1002/aoc.70151
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A samarium‐based metal–organic framework (MOF) containing benzophenone‐4,4′‐dicarboxylate (bpndc) linker was synthesized and characterized using X‐ray crystallography and spectroscopy methods. The crystal structure analysis revealed that the MOF is a three‐dimensional 3‐nodal 5‐c net. The prepared MOF was used as a catalyst in glycerol acetalization to produce solketal as a fuel additive. The catalyst with suitable thermal stability and acidic characteristics resulted in 93.7% glycerol conversion with solketal selectivity of 90.1%. Th
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Hajiashrafi, T., Afzali, N., Tarighi, S., Rudbari, H. A., & Blacque, O. (2025). A Samarium Rod‐MOF With Benzophenone‐4,4´‐Dicarboxylate Linker: A Catalyst for Glycerol Acetalization to Solketal. Applied Organometallic Chemistry, 39(6), e70151. https://doi.org/10.1002/aoc.70151