Publication: Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes
Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes
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Besmer, M. L., Braband, H., Schneider, S., Spingler, B., & Alberto, R. (2021). Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes. Inorganic Chemistry, 60(9), 6696–6701. https://doi.org/10.1021/acs.inorgchem.1c00503
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Dinitrogen (N2) complexes of technetium (99Tc) are rare, and only two examples have been reported. To complement this important class of complexes also for 99Tc, two different pincer-type complexes of 99Tc were studied to assess their abilities for coordinating dinitrogen. The reactions of the 99TcIII complex [99TcCl3(PPh3)2(NCCH3)] with the pincer ligands PNPtBu and PyrPNPtBu respectively gave [99Tc(PNPtBu)Cl2] and [99Tc(PyrPNPtBu)Cl3], the first structurally characterized 99Tc complexes with mer-coordinated pincer ligands. Reduction
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- Besmer, Manuel Luca
- Schneider, Sven
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Besmer, M. L., Braband, H., Schneider, S., Spingler, B., & Alberto, R. (2021). Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes. Inorganic Chemistry, 60(9), 6696–6701. https://doi.org/10.1021/acs.inorgchem.1c00503
