Publication: Azatriseptanes: Strained Framework Analogs of [7,7,7]Circulenes
Azatriseptanes: Strained Framework Analogs of [7,7,7]Circulenes
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Zhang, K., Hope, P. A., El Bitar Nehme, M., Linden, A., Spingler, B., & Rickhaus, M. (2023). Azatriseptanes: Strained Framework Analogs of [7,7,7]Circulenes. Chemistry, 29(14), e202203954. https://doi.org/10.1002/chem.202203954
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The syntheses and characterizations of heptagon-embedded polycyclic aromatic compounds are essential for understanding the effect of negative curvature on carbon allotropes such as fullerene and graphene that have applications in functional organic materials. However, owing to the synthetic difficulties in functionalizing and embedding 7-membered rings, these strain-challenged structures are relatively unexplored. We report here the synthesis and photophysical characterization of a triarylamine core bridged with ethane chains at the 2
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Zhang, K., Hope, P. A., El Bitar Nehme, M., Linden, A., Spingler, B., & Rickhaus, M. (2023). Azatriseptanes: Strained Framework Analogs of [7,7,7]Circulenes. Chemistry, 29(14), e202203954. https://doi.org/10.1002/chem.202203954
