Publication: Chiral Distortion of Confined Ice Oligomers (n= 5,6)
Chiral Distortion of Confined Ice Oligomers (n= 5,6)
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Ma, H., Ding, Y., Iannuzzi, M., Brugger, T., Berner, S., Hutter, J., Osterwalder, J., & Greber, T. (2012). Chiral Distortion of Confined Ice Oligomers (n= 5,6). Langmuir, 28(43), 15246–15250. https://doi.org/10.1021/la302561r
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Ice nuclei have been studied on the hexagonal boron nitride nanomesh (h-BN/Rh(111)), a template with 2 nm wide molecule traps. Scanning tunneling microscopy shows confined clusters, where oligomers with three protrusions are particularly abundant. Together with local barrier height dI/dz maps, it is found that the dipoles of the water molecules arrange in a homodrome, which is consistent with density functional theory calculations. Hydrogen bonds toward the substrate identify h-BN/Rh(111) to be hydrophilic. The substrate distorts the
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- Ma, Haifeng
- Ding, Yun
- Brugger, Thomas
- Berner, Simon
- Hutter, Jürg
- Osterwalder, Jürg
- Greber, Thomas
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Ma, H., Ding, Y., Iannuzzi, M., Brugger, T., Berner, S., Hutter, J., Osterwalder, J., & Greber, T. (2012). Chiral Distortion of Confined Ice Oligomers (n= 5,6). Langmuir, 28(43), 15246–15250. https://doi.org/10.1021/la302561r
