Publication: Catalyst Proximity-Induced Functionalization of h-BN with Quat Derivatives
Catalyst Proximity-Induced Functionalization of h-BN with Quat Derivatives
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Hemmi, A., Cun, H., Tocci, G., Epprecht, A., Stel, B., Lingenfelder, M., de Lima, L. H., Muntwiler, M., Osterwalder, J., Iannuzzi, M., & Greber, T. (2019). Catalyst Proximity-Induced Functionalization of h-BN with Quat Derivatives. Nano Letters, 19(9), 5998–6004. https://doi.org/10.1021/acs.nanolett.9b01792
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Abstract
Inert single-layer boron nitride (h-BN) grown on a catalytic metal may be functionalized with quaternary ammonium compounds (quats) that are widely used as nonreactive electrolytes. We observe that the quat treatment, which facilitates the electrochemical transfer of two-dimensional materials, involves a decomposition of quat ions and leads to covalently bound quat derivatives on top of the 2D layer. Applying tetraoctylammonium and h-BN on rhodium, the reaction product is top-alkylized h-BN as identified with high-resolution X-ray pho
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- Hemmi, Adrian
- Cun, Huanyao
- Tocci, Gabriele
- Epprecht, Adrian
- Stel, Bart
- Lingenfelder, Magalí
- de Lima, Luis Henrique
- Muntwiler, Matthias
- Greber, Thomas
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Hemmi, A., Cun, H., Tocci, G., Epprecht, A., Stel, B., Lingenfelder, M., de Lima, L. H., Muntwiler, M., Osterwalder, J., Iannuzzi, M., & Greber, T. (2019). Catalyst Proximity-Induced Functionalization of h-BN with Quat Derivatives. Nano Letters, 19(9), 5998–6004. https://doi.org/10.1021/acs.nanolett.9b01792
