Publication: A Supramolecular Nanosheet Assembled from Carpyridines and Water
A Supramolecular Nanosheet Assembled from Carpyridines and Water
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Woods, J. F., Zhang, K., Peterschmitt, J., Blacque, O., Santiso-Quinones, G., Samperisi, L., Vargas Jentzsch, A., & Rickhaus, M. (2025). A Supramolecular Nanosheet Assembled from Carpyridines and Water. Journal of the American Chemical Society, 147(22), 18380–18385. https://doi.org/10.1021/jacs.4c17024
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The use of water as a solvent to facilitate supramolecular self-assembly and polymerization is well-documented; however, it is rare that water acts as a monomer that undergoes polymerization. We report the formation of nanosheets composed of water and a saddle-shaped porphyrinoid macrocycle, carpyridine, which allows for linearly stacked, eclipsed columns within formed 2D structures. Self-assembling carpyridine monomers from solutions with different extents of wetness permit the formation of nanosheets that appear identical by microsc
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Woods, J. F., Zhang, K., Peterschmitt, J., Blacque, O., Santiso-Quinones, G., Samperisi, L., Vargas Jentzsch, A., & Rickhaus, M. (2025). A Supramolecular Nanosheet Assembled from Carpyridines and Water. Journal of the American Chemical Society, 147(22), 18380–18385. https://doi.org/10.1021/jacs.4c17024
