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Reaction Intermediates Involved in the Epoxidation of Ethylene Over Silver Revealed by In Situ Photoelectron Spectroscopy

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Date
2025
Journal Article
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Guo, M., Dongfang, N., Liu, Q., Iannuzzi, M., van Bokhoven, J. A., & Artiglia, L. (2025). Reaction Intermediates Involved in the Epoxidation of Ethylene Over Silver Revealed by In Situ Photoelectron Spectroscopy. Small, 21, e2408432. https://doi.org/10.1002/smll.202408432

Abstract

Abstract

Abstract

Ethylene oxide (EO) is a crucial building block in the chemical industry, and its production via ethylene epoxidation (EPO) is a pivotal process. Silver‐based catalysts are known for their high selectivity and are currently largely used in the industrial process. Extensive research over the past 20 years has assumed the oxametallacycle (OMC) as a reaction intermediate, implying that ethylene reacts with adsorbed oxygen on the surface of silver. The OMC is suggested to be the common intermediate for both EO and acetaldehyde, with the l

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57 since deposited on 2025-04-18
Acq. date: 2025-11-12

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21

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Number
5

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e2408432

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Journal Article

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English

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2025-02-01

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2025-04-18

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1613-6810

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Closed

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57 since deposited on 2025-04-18
Acq. date: 2025-11-12

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Guo, M., Dongfang, N., Liu, Q., Iannuzzi, M., van Bokhoven, J. A., & Artiglia, L. (2025). Reaction Intermediates Involved in the Epoxidation of Ethylene Over Silver Revealed by In Situ Photoelectron Spectroscopy. Small, 21, e2408432. https://doi.org/10.1002/smll.202408432

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