Publication: Direct Synthesis of Non-Alkyl Functionalized Bis-Arene Complexes of Rhenium and 99(m)Technetium
Direct Synthesis of Non-Alkyl Functionalized Bis-Arene Complexes of Rhenium and 99(m)Technetium
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Hernández-Valdés, D., Meola, G., Braband, H., Spingler, B., & Alberto, R. (2018). Direct Synthesis of Non-Alkyl Functionalized Bis-Arene Complexes of Rhenium and 99(m)Technetium. Organometallics, 37(17), 2910–2916. https://doi.org/10.1021/acs.organomet.8b00494
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The synthesis of technetium and rhenium bis-arene sandwich complexes, [M(η6-C6H6)2]+, requires AlCl3 according to Fischer–Hafner conditions. Its high reactivity limits syntheses to alkylated aromatic hydrocarbons but is generally incompatible with aromatic hydrocarbons, bearing heteroatoms in their side chains “R”. In a nuclear medical context, a synthesis to complexes of the [M(η6-C6H5-R)2]+ type directly from [ReO4]− or [99mTcO4]− is desirable because postsynthetic derivatizations are not possible for 99mTc. Here, we present direct
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- Hernández-Valdés, Daniel
- Meola, Giuseppe
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Hernández-Valdés, D., Meola, G., Braband, H., Spingler, B., & Alberto, R. (2018). Direct Synthesis of Non-Alkyl Functionalized Bis-Arene Complexes of Rhenium and 99(m)Technetium. Organometallics, 37(17), 2910–2916. https://doi.org/10.1021/acs.organomet.8b00494