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Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology

Date

Date

Date
2020
Journal Article
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Senior, L., & Linden, A. (2020). Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology. Polyhedron, 184, 114564. https://doi.org/10.1016/j.poly.2020.114564

Abstract

Abstract

Abstract

Bi(III) as its oxide combined with 2,4,6-pyridine tricarboxylic acid, H2pdc-COOH, and various pyridine-derived additives in dimethylformamide (dmf) under solvothermal conditions produced three novel bismuth coordination polymers, {[Bi(μ-pdc-COO)2][NH2Me2]3}n, 1, {[Bi(μ-pdc-COO)2][C5H7N2]3·C5H6N2}n, 2, and {[Bi2(μ-pdc-COO)2(μ-pdc-COOH)(pdc-COOH)][NH2Me2]4·2dmf·NHMe2}n, 3. The anionic coordination network topologies are two-dimensional, chains-of-loops and ladders, respectively, but the local 8-coordinate environments about the bismuth(

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80 since deposited on 2020-05-20
Acq. date: 2025-11-12

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147 since deposited on 2020-05-20
Acq. date: 2025-11-12

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Journal/Series Title

Journal/Series Title

Journal/Series Title

Volume

Volume

Volume
184

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Page range/Item number

Page range/Item number
114564

Item Type

Item Type

Item Type
Journal Article

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Dewey Decimal Classifikation

Dewey Decimal Classifikation

Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Materials Chemistry, Bismuth, 2, 4, 6-pyridine tricarboxylic acid, 2, 6-pyridine dicarboxylic acid, Framework, MOF, Structural characterization

Language

Language

Language
English

Publication date

Publication date

Publication date
2020-07-01

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Date available
2020-05-20

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Publisher

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ISSN or e-ISSN
0277-5387

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OA Status
Hybrid

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Downloads

80 since deposited on 2020-05-20
Acq. date: 2025-11-12

Views

147 since deposited on 2020-05-20
Acq. date: 2025-11-12

Citations

Citation copied

Senior, L., & Linden, A. (2020). Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology. Polyhedron, 184, 114564. https://doi.org/10.1016/j.poly.2020.114564

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