Publication: Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology
Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology
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Senior, L., & Linden, A. (2020). Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology. Polyhedron, 184, 114564. https://doi.org/10.1016/j.poly.2020.114564
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Bi(III) as its oxide combined with 2,4,6-pyridine tricarboxylic acid, H2pdc-COOH, and various pyridine-derived additives in dimethylformamide (dmf) under solvothermal conditions produced three novel bismuth coordination polymers, {[Bi(μ-pdc-COO)2][NH2Me2]3}n, 1, {[Bi(μ-pdc-COO)2][C5H7N2]3·C5H6N2}n, 2, and {[Bi2(μ-pdc-COO)2(μ-pdc-COOH)(pdc-COOH)][NH2Me2]4·2dmf·NHMe2}n, 3. The anionic coordination network topologies are two-dimensional, chains-of-loops and ladders, respectively, but the local 8-coordinate environments about the bismuth(
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Senior, L., & Linden, A. (2020). Coordination polymers incorporating Bi(III) and 2,4,6-pyridine tricarboxylic acid and its derivatives: Synthesis, structure and topology. Polyhedron, 184, 114564. https://doi.org/10.1016/j.poly.2020.114564