Publication: Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics
Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics
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Zhang, K., Shen, Y., Yang, X., Liu, J., Jiang, T., Finney, N. S., Spingler, B., & Duttwyler, S. (2019). Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics. Chemistry - A European Journal, 25(37), 8754–8759. https://doi.org/10.1002/chem.201900584
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The weakly coordinating cluster [CB11H12]− is used as a versatile building block for the preparation of luminescent copper(I) complexes. Treatment of [CB11H11‐12‐C≡CH]− with CuI and ammonia affords {(CB11H11‐12‐C≡C)2Cu4(NH3)3}n (2). Addition of selected phosphine and pyridine ligands transforms 2 to a range of homometallic products 3–13. All compounds have been characterized by X‐ray crystallography, which reveals a surprising variety of structural complexity featuring cores with two to ten Cu+ centers. In the solid state, products 3–
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- Zhang, Kang
- Shen, Yunjun
- Yang, Xiaoli
- Liu, Jiyong
- Jiang, Tao
- Finney, Nathaniel S
- Duttwyler, Simon
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Zhang, K., Shen, Y., Yang, X., Liu, J., Jiang, T., Finney, N. S., Spingler, B., & Duttwyler, S. (2019). Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics. Chemistry - A European Journal, 25(37), 8754–8759. https://doi.org/10.1002/chem.201900584
