Publication: Tunable Light‐Emission Properties of Solution‐Processable N‐Heterocyclic Carbene Cyclometalated Gold(III) Complexes for Organic Light‐Emitting Diodes
Tunable Light‐Emission Properties of Solution‐Processable N‐Heterocyclic Carbene Cyclometalated Gold(III) Complexes for Organic Light‐Emitting Diodes
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Malmberg, R., von Arx, T., Hasan, M., Blacque, O., Shukla, A., McGregor, S. K. M., Lo, S., Namdas, E. B., & Venkatesan, K. (2021). Tunable Light‐Emission Properties of Solution‐Processable N‐Heterocyclic Carbene Cyclometalated Gold(III) Complexes for Organic Light‐Emitting Diodes. Chemistry, 27(25), 7265–7274. https://doi.org/10.1002/chem.202100215
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N-Heterocyclic carbene (NHC) cyclometalated gold(III) complexes remain very scarce and therefore their photophysical properties remain currently underexplored. Moreover, gold(III) complexes emitting in the blue region of the electromagnetic spectrum are rare. In this work, a series of four phosphorescent gold(III) complexes was investigated bearing four different NHC monocyclometalated (C<^>C*)-type ligands and a dianionic (N<^>N)-type ancillary ligand ((N<^>N)= 5,5'-(propane-2,2-diyl)bis(3-(trifluoromethyl)-1H-pyrazole) (mepzH$_2$
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Malmberg, R., von Arx, T., Hasan, M., Blacque, O., Shukla, A., McGregor, S. K. M., Lo, S., Namdas, E. B., & Venkatesan, K. (2021). Tunable Light‐Emission Properties of Solution‐Processable N‐Heterocyclic Carbene Cyclometalated Gold(III) Complexes for Organic Light‐Emitting Diodes. Chemistry, 27(25), 7265–7274. https://doi.org/10.1002/chem.202100215