Publication: Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C–H Auration
Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C–H Auration
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Biedrzycki, M., Martín, J., Genoux, A., Boschi, E., & Nevado, C. (2025). Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C–H Auration. ACS Organic & Inorganic Au, 5(5), 322–327. https://doi.org/10.1021/acsorginorgau.5c00057
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A new method for the synthesis of cyclometalated gold-(III) complexes featuring (P^N^C) ligands is reported. This protocol employs a tandem oxidative addition/cycloauration process, enabling the formation of (P^N^C)-gold-(III)-aryl, -alkenyl and -alkynyl derivatives by creating two Au-C bonds in one pot from a structurally diverse range of C-(sp)- and C-(sp)-iodide substrates. Additionally, a complementary two-step method was developed to access (P^N^C)-gold-(III)-alkynyl complexes, which exhibit emission in the blue and green light r
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Biedrzycki, M., Martín, J., Genoux, A., Boschi, E., & Nevado, C. (2025). Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C–H Auration. ACS Organic & Inorganic Au, 5(5), 322–327. https://doi.org/10.1021/acsorginorgau.5c00057
