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Stereoselective carboperfluoroalkylation of internal alkynes: mechanistic insights


Li, Zhaodong; Merino, Estíbaliz; Nevado, Cristina (2017). Stereoselective carboperfluoroalkylation of internal alkynes: mechanistic insights. Topics in Catalysis, 60(8):545-553.

Abstract

A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a regio- and stereoselective manner. Mechanistic studies have been carried out to shed light on the nature of the likely intermediates involved in these transformations.

Abstract

A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a regio- and stereoselective manner. Mechanistic studies have been carried out to shed light on the nature of the likely intermediates involved in these transformations.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > General Chemistry
Language:English
Date:2017
Deposited On:04 Jan 2018 19:42
Last Modified:28 Jul 2020 12:24
Publisher:Springer
ISSN:1022-5528
OA Status:Closed
Publisher DOI:https://doi.org/10.1007/s11244-017-0743-y

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