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Microwave‐assisted reduction of aromatic nitro compounds with novel oxo‐rhenium complexes


Grieco, Gabriele; Blacque, Olivier (2022). Microwave‐assisted reduction of aromatic nitro compounds with novel oxo‐rhenium complexes. Applied Organometallic Chemistry, 36(1):e6452.

Abstract

The reduction of several aromatic nitro compounds to amines by means of the two novel catalytic systems ([IMes](2)ReOBr3)/PhSiH3 and ([Py](3)ReNOBr2)/PhSiH3 under microwave irradiation is here reported. These two systems were able to perform the reduction of nitro groups with higher TON and TOF when compared with previously reported systems based on oxo-rhenium core under standard heating, although they showed a lesser broad reaction scope compared with the known systems.

Abstract

The reduction of several aromatic nitro compounds to amines by means of the two novel catalytic systems ([IMes](2)ReOBr3)/PhSiH3 and ([Py](3)ReNOBr2)/PhSiH3 under microwave irradiation is here reported. These two systems were able to perform the reduction of nitro groups with higher TON and TOF when compared with previously reported systems based on oxo-rhenium core under standard heating, although they showed a lesser broad reaction scope compared with the known systems.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Chemistry
Physical Sciences > Inorganic Chemistry
Uncontrolled Keywords:Inorganic Chemistry, General Chemistry
Language:English
Date:1 January 2022
Deposited On:13 Jan 2022 14:29
Last Modified:25 Feb 2024 02:44
Publisher:Wiley-Blackwell Publishing, Inc.
ISSN:0268-2605
OA Status:Hybrid
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1002/aoc.6452
Project Information:
  • : FunderUniversität Zürich
  • : Grant ID
  • : Project Title
  • Content: Published Version
  • Language: English
  • Licence: Creative Commons: Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)