Valenta, Leoš; Mayländer, Maximilian; Kappeler, Pia; Blacque, Olivier; Šolomek, Tomáš; Richert, Sabine; Juricek, Michal (2022). Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon. Chemical Communications, 58(18):3019-3022.
Triangulene, known as Clar’s hydrocarbon, is a prototypical non-Kekule ́ diradical comprised of six benzenoid rings fused in a trian-gular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suffice to protect all reactive positions. This work brings prospects to use triangulene and its open-shell analogs in spintronic materials via solution-phase synthesis.
Triangulene, known as Clar’s hydrocarbon, is a prototypical non-Kekule ́ diradical comprised of six benzenoid rings fused in a trian-gular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suffice to protect all reactive positions. This work brings prospects to use triangulene and its open-shell analogs in spintronic materials via solution-phase synthesis.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Uncontrolled Keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Language: | English |
| Date: | 1 January 2022 |
| Deposited On: | 10 Jan 2023 14:14 |
| Last Modified: | 07 Feb 2023 13:24 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| OA Status: | Hybrid |
| Free access at: | PubMed ID. An embargo period may apply. |
| Publisher DOI: | https://doi.org/10.1039/d2cc00352j |
| PubMed ID: | 35156113 |
Valenta, Leoš